http://answers.com/topic/list-of-james-bond-villiansFilm
Villain
Portrayed by
Dr. No
Dr. Julius No (for S.P.E.C.T.R.E.)
Joseph Wiseman

From Russia with Love
Rosa Klebb Ernst Stavro Blofeld
Lotte Lenya Anthony Dawson (hands) Eric Pohlmann (voice)

Goldfinger
Auric Goldfinger
Gert Fröbe

Thunderball
Emilio Largo Ernst Stavro Blofeld
Adolfo Celi Anthony Dawson (hands) Eric Pohlmann (voice)

You Only Live Twice
Ernst Stavro Blofeld
Donald Pleasence

On Her Majesty's Secret Service
Ernst Stavro Blofeld
Telly Savalas

Diamonds Are Forever
Ernst Stavro Blofeld
Charles Gray

Live and Let Die
Dr. Kananga / Mr. Big
Yaphet Kotto

The Man with the Golden Gun
Francisco Scaramanga
Christopher Lee

The Spy Who Loved Me
Karl Stromberg
Curt Jurgens

Moonraker
Sir Hugo Drax
Michael Lonsdale

For Your Eyes Only
Aristotle Kristatos
Julian Glover

Octopussy
Kamal Khan General Orlov
Louis Jourdan Steven Berkoff

A View to a Kill
Max Zorin
Christopher Walken

The Living Daylights
Brad Whitaker General Georgi Koskov
Joe Don Baker Jeroen Krabbé

Licence to Kill
Franz Sanchez
Robert Davi

GoldenEye
Alec Trevelyan
Sean Bean

Tomorrow Never Dies
Elliot Carver
Jonathan Pryce

The World Is Not Enough
Viktor 'Renard' Zokas Elektra King
Robert Carlyle Sophie Marceau

Die Another Day
Gustav Graves / (Colonel Moon)
Toby Stephens / (Will Yun Lee)

Casino Royale 2006 version
Le Chiffre Steven Obanno
Mads Mikkelsen Isaach De Bankolé